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52Te127.6 u

Tellurium

metalloid
Atomic Number
52
Atomic Mass
127.6 u
Period
5
Group
16

Quick Facts

PropertyValue
SymbolTe
Atomic Number52
Atomic Mass127.60 u
CategoryMetalloid
Period5
Group16
Blockp
Electron Configuration[Kr] 4d¹⁰ 5s² 5p⁴

Physical Properties

PropertyValue
State at 20°CSolid
Density6.24 g/cm³
Melting Point449.51°C (722.66 K)
Boiling Point988°C (1261 K)
AppearanceSilvery-white, brittle, crystalline

Atomic Properties

PropertyValue
Electron Configuration[Kr] 4d¹⁰ 5s² 5p⁴
Electronegativity2.1 (Pauling scale)
First Ionization Energy869.3 kJ/mol
Atomic Radius140 pm
Covalent Radius138 pm
Van der Waals Radius206 pm

History and Discovery

Discovered by: Franz-Joseph Müller von Reichenstein Year of Discovery: 1783 Location: Transylvania (modern Romania)

Etymology

Named from Latin "tellus" meaning "earth" or "ground." Martin Heinrich Klaproth named it in 1798.

Discovery Story

Franz-Joseph Müller von Reichenstein discovered tellurium in 1783 while analyzing gold ore from Transylvania. He recognized it as a new element but could not isolate it. Martin Heinrich Klaproth confirmed the discovery in 1798 and named it tellurium.

Isotopes

IsotopeNatural AbundanceHalf-lifeDecay Mode
¹²⁰Te0.09%Stable-
¹²²Te2.55%Stable-
¹²³Te0.89%>9.2 × 10¹⁶ yearsEC
¹²⁴Te4.74%Stable-
¹²⁵Te7.07%Stable-
¹²⁶Te18.84%Stable-
¹²⁸Te31.74%2.2 × 10²⁴ yearsβ⁻β⁻
¹³⁰Te34.08%7.9 × 10²⁰ yearsβ⁻β⁻

Occurrence

Natural Abundance

Tellurium is very rare, comprising only about 0.001 ppm of Earth's crust (rarer than gold). It occurs in native form, telluride ores, and with copper and gold ores.

Extraction and Production

  • Byproduct: Almost entirely from copper refining
  • Anode Slimes: Recovered from electrolytic copper refining
  • Sources: Copper smelters worldwide
  • Global production: about 500 tons annually

Applications and Uses

Photovoltaics

  • Cadmium telluride (CdTe) solar cells (fastest-growing use)
  • Thin-film solar panels
  • High efficiency at lower cost

Metallurgy

  • Steel and copper alloys (improves machinability)
  • Lead alloys (batteries)
  • Cast iron additive

Thermoelectrics

  • Bismuth telluride cooling devices
  • Thermoelectric generators
  • Solid-state refrigeration

Other Uses

  • Vulcanizing agent for rubber
  • Glass and ceramic colorant (blue)
  • Infrared detectors

Biological Role

Tellurium has no known biological role and is toxic.

In the Human Body

Tellurium is not normally present in the body. Exposure causes "garlic breath" due to dimethyl telluride formation.

Toxicity

Tellurium compounds are toxic. Hydrogen telluride (H₂Te) is extremely poisonous.

Safety and Hazards

Toxicity

Tellurium and its compounds are moderately toxic. The characteristic "garlic breath" indicates exposure. More toxic than selenium.

Handling Precautions

  • Avoid inhalation of dust
  • Hydrogen telluride is extremely toxic
  • "Tellurium breath" persists for weeks after exposure
  • Use appropriate ventilation

Environmental Impact

Tellurium is rare. Solar panel recycling and electronic waste are emerging concerns for tellurium recovery.

Interesting Facts

  1. Tellurium was discovered before selenium, though selenium appears before it in the periodic table
  2. Exposure to tellurium causes persistent garlic-like breath odor
  3. Tellurium is rarer than gold in Earth's crust
  4. CdTe solar cells are among the lowest-cost solar technologies
  5. The element is named after Earth, while selenium (above it) is named after the Moon