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1H1.008 u

Hydrogen

nonmetal
Atomic Number
1
Atomic Mass
1.008 u
Period
1
Group
1

Quick Facts

PropertyValue
SymbolH
Atomic Number1
Atomic Mass1.008 u
CategoryNonmetal
Period1
Group1
Blocks
Electron Configuration1s¹

Physical Properties

PropertyValue
State at 20°CGas
Density0.00008988 g/cm³
Melting Point-259.16°C (14.01 K)
Boiling Point-252.87°C (20.28 K)
AppearanceColorless, odorless gas

Atomic Properties

PropertyValue
Electron Configuration1s¹
Electronegativity2.20 (Pauling scale)
First Ionization Energy1312.0 kJ/mol
Atomic Radius53 pm
Covalent Radius31 pm
Van der Waals Radius120 pm

History and Discovery

Discovered by: Henry Cavendish Year of Discovery: 1766 Location: London, England

Etymology

The name "hydrogen" comes from the Greek words "hydro" (water) and "genes" (forming), meaning "water-former." Antoine Lavoisier named it in 1783 after observing that burning hydrogen produces water.

Discovery Story

Henry Cavendish first recognized hydrogen as a distinct substance in 1766, calling it "inflammable air." He discovered that it produced water when burned, a crucial observation. Earlier, Robert Boyle had produced hydrogen in 1671 by reacting iron filings with dilute acids, but did not recognize it as a unique element. Lavoisier later gave hydrogen its modern name and proved it was an element.

Isotopes

IsotopeNatural AbundanceHalf-lifeDecay Mode
¹H (Protium)99.98%Stable-
²H (Deuterium)0.02%Stable-
³H (Tritium)Trace12.32 yearsβ⁻

Occurrence

Natural Abundance

Hydrogen is the most abundant element in the universe, comprising about 75% of all normal matter by mass. On Earth, it is the third most abundant element on the surface, primarily found in water (H₂O) and organic compounds. Free hydrogen gas is rare in Earth's atmosphere (less than 1 ppm) because it escapes into space.

Extraction and Production

  • Steam Reforming: Most commercial hydrogen is produced by reacting natural gas with steam at high temperatures
  • Electrolysis: Splitting water using electricity produces high-purity hydrogen
  • Coal Gasification: Reacting coal with oxygen and steam
  • Biological Production: Certain algae and bacteria can produce hydrogen

Applications and Uses

Industrial Applications

  • Ammonia synthesis (Haber-Bosch process) for fertilizers
  • Petroleum refining (hydrocracking and hydrodesulfurization)
  • Methanol production
  • Hydrogenation of fats and oils

Energy Applications

  • Hydrogen fuel cells for vehicles and power generation
  • Rocket propellant (liquid hydrogen with liquid oxygen)
  • Energy storage medium for renewable energy

Technological Applications

  • Semiconductor manufacturing
  • Welding and cutting metals (hydrogen torch)
  • Cooling agent for electrical generators

Other Uses

  • Weather balloons
  • Reducing agent in metallurgy
  • Hydrogen peroxide production

Biological Role

Hydrogen is essential for life. It is a component of water and all organic molecules including carbohydrates, proteins, lipids, and nucleic acids.

In the Human Body

  • Approximately 10% of human body mass is hydrogen
  • Essential component of water (60-70% of body weight)
  • Found in all organic molecules in the body
  • Critical for pH balance and cellular functions

Dietary Sources

Hydrogen is obtained through water and all food sources, as it is present in virtually all organic compounds.

Safety and Hazards

Toxicity

Hydrogen gas is non-toxic but can act as a simple asphyxiant by displacing oxygen in enclosed spaces.

Handling Precautions

  • Highly flammable gas - ignites easily in air (4-75% concentration range)
  • Forms explosive mixtures with air and oxygen
  • Store and handle away from heat, sparks, and open flames
  • Use proper ventilation
  • Invisible flame when burning

Environmental Impact

Hydrogen is environmentally benign. When burned, it produces only water vapor with no carbon emissions, making it an attractive clean energy carrier.

Interesting Facts

  1. Hydrogen is the lightest and simplest element, with just one proton and one electron
  2. The Sun converts about 600 million tons of hydrogen into helium every second through nuclear fusion
  3. Liquid hydrogen is used as rocket fuel because of its high energy-to-weight ratio
  4. Hydrogen was used in early airships (like the Hindenburg) before being replaced by helium due to flammability
  5. A cubic meter of water contains about 111 kg of hydrogen