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29Cu63.546 u

Copper

transition metal
Atomic Number
29
Atomic Mass
63.546 u
Period
4
Group
11

Quick Facts

PropertyValue
SymbolCu
Atomic Number29
Atomic Mass63.546 u
CategoryTransition Metal
Period4
Group11
Blockd
Electron Configuration[Ar] 3d¹⁰ 4s¹

Physical Properties

PropertyValue
State at 20°CSolid
Density8.96 g/cm³
Melting Point1084.62°C (1357.77 K)
Boiling Point2562°C (2835 K)
AppearanceReddish-orange metallic

Atomic Properties

PropertyValue
Electron Configuration[Ar] 3d¹⁰ 4s¹
Electronegativity1.90 (Pauling scale)
First Ionization Energy745.5 kJ/mol
Atomic Radius128 pm
Covalent Radius132 pm
Van der Waals Radius140 pm

History and Discovery

Discovered by: Known since antiquity Year of Discovery: ~9000 BCE Location: Middle East

Etymology

The symbol "Cu" comes from Latin "cuprum," derived from "aes cyprium" (metal from Cyprus), as Cyprus was a major copper source in the ancient Mediterranean.

Discovery Story

Copper was one of the first metals used by humans, with artifacts dating back to 9000 BCE. The Copper Age (Chalcolithic) preceded the Bronze Age. Ancient civilizations in Mesopotamia, Egypt, and the Indus Valley extensively used copper and bronze.

Isotopes

IsotopeNatural AbundanceHalf-lifeDecay Mode
⁶³Cu69.17%Stable-
⁶⁵Cu30.83%Stable-

Occurrence

Natural Abundance

Copper comprises about 60 ppm of Earth's crust. It sometimes occurs in native (metallic) form. Major ores are chalcopyrite (CuFeS₂), bornite, and malachite. Major producers are Chile, Peru, China, and the United States.

Extraction and Production

  • Pyrometallurgy: Smelting of sulfide ores
  • Hydrometallurgy: Leaching and electrowinning
  • Recycling: About 35% of copper use is recycled
  • Global production: about 21 million tons annually

Applications and Uses

Electrical Applications

  • Electrical wiring (60% of copper use)
  • Electric motors and generators
  • Power transmission
  • Electronics and circuit boards

Construction

  • Plumbing pipes and fittings
  • Roofing and flashing
  • Architectural elements

Transportation

  • Automobile wiring and radiators
  • Electric vehicle motors and batteries
  • Marine applications

Other Uses

  • Coins and currency
  • Cookware
  • Antimicrobial surfaces
  • Alloys (bronze, brass)

Biological Role

Copper is an essential trace element for all living organisms. It is a cofactor for numerous enzymes.

In the Human Body

  • About 100 mg in adult body
  • Essential for iron metabolism
  • Required for connective tissue formation
  • Important for nervous system function
  • Daily requirement: 0.9 mg

Dietary Sources

Shellfish, nuts, seeds, whole grains, beans, and organ meats are rich in copper.

Safety and Hazards

Toxicity

Copper is essential but toxic in excess (Wilson's disease is a genetic copper accumulation disorder). Copper sulfate is poisonous if ingested.

Handling Precautions

  • Copper dust can irritate respiratory tract
  • Molten copper poses severe burn risk
  • Some copper compounds are skin irritants
  • Welding copper produces harmful fumes

Environmental Impact

Copper mining can cause significant environmental damage. Copper in water is toxic to aquatic organisms at low concentrations.

Interesting Facts

  1. Copper was the first metal to be smelted from ore (around 5000 BCE)
  2. The Statue of Liberty contains 80 tons of copper
  3. Copper surfaces kill bacteria within hours (antimicrobial properties)
  4. Copper is 100% recyclable without losing quality
  5. An average home contains about 200 kg of copper